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Low-frequency critical dynamics in (CnH2n+1NH3)2SnCl6 model biomembrane systems

Low-frequency critical dynamics in (CnH2n+1NH3)2SnCl6 model biomembrane systems

초록/요약

Nuclear magnetic resonance has been employed as a probe for the collective hydrocarbon chain dynamics in the organicinorganicmodel biomembranes (CnH 2n+1NH 3)2SnCl6, undergoing orderdisorder and conformational phase transitions. No anomalies wereobserved in the laboratory-frame spinlattice relaxation measurements at the orderdisorder phase transitions, whereas a discontinuitywas manifest at the conformational phase transitions characteristic of a rst-order phase transition. On the other hand, our rotatingframe spinlattice relaxation measurements revealed a low-frequency critical collective chain dynamics in the kilohertz regime associatedwith the orderdisorder phase transition.

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